Primary and secondary seals, and which one matters when
The two seals do different jobs and people frequently attribute one’s function to the other.
The primary seal of polyisobutylene is the barrier. It is what keeps argon in and water vapour out, and its performance depends on the width and continuity of the bead. The secondary seal is structural: it bonds the panes to the spacer so the unit behaves as one component under wind load and thermal movement. Polysulphide is the traditional secondary seal and it retains gas well but degrades under ultraviolet. Silicone resists ultraviolet indefinitely and is required where the seal is exposed, but it is more permeable to gas. Which one is correct depends entirely on how much of the edge the frame covers.